Tris(2-pyridyl)phosphine as a versatile ligand for pnictogen acceptors
Author:
Affiliation:
1. Department of Chemistry
2. University of Victoria
3. Victoria
4. Canada
5. University of Alberta
6. Edmonton
7. Department of Chemistry and Applied Biosciences
8. ETH Zurich
9. CH-8093 Zurich
10. Switzerland
Abstract
We report cationic complexes of arsenic and antimony with the tris(2-pyridyl)phosphine ligand. Chloride ion abstraction from the main group halide using TMSOTf in presence of the ligand gives [P(Pyr)3Pn][OTf]3, in which the trication adopts a Janus Head type complex with a C3v symmetric cage structure and two apical lone pairs.
Funder
Natural Sciences and Engineering Research Council of Canada
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01526G
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