In situ-created Mn(iii) complexes active for liquid-phase oxidation of alkylaromatics to aromatic ketones with molecular oxygen-Reference-Cited by-同舟云学术

In situ-created Mn(iii) complexes active for liquid-phase oxidation of alkylaromatics to aromatic ketones with molecular oxygen

Published:2016 Issue:2 Volume:6 Page:442-448
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Kuwahara Yasutaka¹²³⁴⁵,Yoshimura Yukihiro¹²³⁴⁵,Yamashita Hiromi¹²³⁴⁵

Affiliation:

1. Division of Materials and Manufacturing Science

2. Graduate School of Engineering

3. Osaka University

4. Suita

5. Japan

Abstract

Mn(OH)_x supported on oxides in situ transforms into a monomeric Mn(iii) species coordinated with the PhCOO⁻ ligand, which efficiently oxidizes alkylaromatics with O₂.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CY/C5CY01308A

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