Dimethylphosphinate bridged binuclear Rh(i) catalysts for the alkoxycarbonylation of aromatic C

Dimethylphosphinate bridged binuclear Rh(i) catalysts for the alkoxycarbonylation of aromatic C–H bonds

Published:2016 Issue:42 Volume:45 Page:16955-16965
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Iturmendi Amaia¹²³⁴,Sanz Miguel Pablo J.¹²³⁴^ORCID,Popoola Saheed A.⁵⁶⁷⁸,Al-Saadi Abdulaziz A.⁵⁶⁷⁸,Iglesias Manuel¹²³⁴,Oro Luis A.¹²³⁴⁹

Affiliation:

1. Departamento de Química Inorgánica – Instituto de Síntesis Química y Catálisis Homogénea-ISQCH

2. Universidad de Zaragoza – CSIC

3. 50009 Zaragoza

4. Spain

5. Chemistry Department

6. King Fahd University of Petroleum and Minerals

7. Dhahran 31261

8. Saudi Arabia

9. Center of Research Excellence in Petroleum Refining & Petrochemicals

Abstract

A variety of binuclear rhodium(i) complexes featuring two bridging dimethylphosphinate ligands ((CH₃)₂PO₂⁻) have been prepared and tested in the alkoxycarbonylation of aromatic C–H bonds.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT03010F

Reference58 articles.

1. The [3 + 3]-Cycloaddition Alternative for Heterocycle Syntheses: Catalytically Generated Metalloenolcarbenes as Dipolar Adducts

2. A new class of binucleating tetratertiaryphosphine ligands. The synthesis and crystallographic characterization of the chiral diastereomer of a rhodium(I) dimer: Rh2Cl2(CO)2(eLTTP) (eLTTP = (Et2PCH2CH2)(Ph)PCH2P(Ph)(CH2CH2PEt2))

3. A Bimetallic Hydroformylation Catalyst: High Regioselectivity and Reactivity Through Homobimetallic Cooperativity

4. Bimetallic hydroformylation: a zwitterionic Rh? I Rh I tetraphosphine ligand-based bimetallic complex exhibiting facile CO addition and phosphine ligand rearrangement equilibrium

5. Hydroformylierungskatalyse: In-situ-Charakterisierung eines zweikernigen Dihydridorhodium(II)-Komplexes mit der bisher größten gemessenen Rh-H-NMR-Kopplungskonstante

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