Photocatalyzed Dowd–Beckwith radical-polar crossover reaction for the synthesis of medium-sized carbocyclic compounds

Author:

Singha Tushar1ORCID,Kadam Ganesh Arjun1ORCID,Hari Durga Prasad1ORCID

Affiliation:

1. Department of Organic Chemistry, Indian Institute of Science, Bangalore, 560012, India

Abstract

A redox-neutral decarboxylative Dowd–Beckwith radical-polar crossover strategy has been developed to access medium-sized rings. The method shows broad applicability across a range of nucleophiles and redox-active esters with various ring sizes.

Funder

Indian Institute of Science

Science and Engineering Research Board

Ministry of Education, India

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference45 articles.

1. J.Cossy , S.Arseniyadis , C.Meyer and R. H.Grubbs , Metathesis in Natural Product Synthesis: Strategies, Substrates and Catalysts , Wiley , 2011 , pp. 1–43

2. Rhodium-Catalyzed Asymmetric Amination of Allylic Trichloroacetimidates

3. K. T.de Oliveira , B. M.Servilha , L. de C.Alves , A. L.Desiderá and T. J.Brocksom , in Stud. Nat. Prod. Chem. , ed. R. Atta ur , Elsevier , 2014 , vol. 42 , pp. 421–463

4. Recent Advances in the Total Synthesis of Natural Products Containing Eight-Membered Carbocycles (2009–2019)

5. The synthesis of seven- and eight-membered rings by radical strategies

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