Adsorption parameters and phase behaviour of non-ionic surfactants at liquid interfaces
Author:
Affiliation:
1. Department of Chemical Engineering and Biotechnology
2. Cambridge University
3. CB3 0AS Cambridge
4. UK
5. Laboratory of Chemical Physics and Engineering
6. Faculty of Chemistry and Pharmacy
7. Sofia University
8. 1164 Sofia
9. Bulgaria
Abstract
A reasonable adsorption model is one that allows all adsorption parameters (adsorption constant, hard-disc area α, attraction parameter β) of a surfactant at a liquid interface to be predicted accurately as a function of the molecular structure and medium conditions.
Funder
BP
Publisher
Royal Society of Chemistry (RSC)
Subject
Condensed Matter Physics,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/SM/C7SM01370A
Reference101 articles.
1. V. B. Fainerman , R.Miller , E. V.Aksenenko and A. V.Makievski , in Surfactants – Chemistry, Interfacial Properties, Applications , ed. V. B. Fainerman , D. Möbius and R. Miller , Elsevier , 2001 , ch. 3
2. Influence of Conformational Free Energy of Hydrocarbon Chains on Adsorption of Nonionic Surfactants at the Air/Solution Interface
3. Effect of molecular structure of amphiphiles on the surface pressure and electric surface potential isotherms at the air/solution interface
4. Interpretation of negative values of the interaction parameter in the adsorption equation through the effects of surface layer heterogeneity
5. Interpretation of surface-tension isotherms of n-alkanoic (fatty) acids by means of the van der Waals model
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