Spin frustration in antiperovskite systems: (TTF˙+ or TSF˙+)3[(Mo6X14)2−Y−]

Author:

Hiramatsu Takaaki1234,Yoshida Yukihiro1234,Saito Gunzi12345,Otsuka Akihiro6784,Yamochi Hideki6784,Shimizu Yasuhiro91011124,Hattori Yuma1311144,Nakamura Yuto1311144,Kishida Hideo1311144,Ito Hiroshi1311144,Kirakci Kaplan15161718,Cordier Stéphane15161718,Perrin Christiane15161718

Affiliation:

1. Faculty of Agriculture

2. Meijo University

3. Nagoya 468-8502

4. Japan

5. Toyota Physical and Chemical Research Institute

6. Research Center for Low Temperature and Materials Sciences

7. Kyoto University

8. Kyoto 606-8501

9. Department of Physics

10. Graduate School of Science

11. Nagoya University

12. Nagoya 464-8602

13. Department of Applied Physics

14. Nagoya 464-8603

15. Institut des Sciences Chimiques de Rennes

16. UMR CNRS 6226

17. 35042 Rennes cedex

18. France

Abstract

We report two novel antiperovskite charge-transfer solids, (TSF)3[(Mo6X14)X] (X = Cl, Br), and discuss spin frustration of their octahedral spin lattices.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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