Role of imine isomerization in the stereocontrol of the Staudinger reaction between ketenes and imines-Reference-Cited by-同舟云学术

Role of imine isomerization in the stereocontrol of the Staudinger reaction between ketenes and imines

Published:2022 Issue:1 Volume:12 Page:104-117
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Cossío Fernando P.¹²³^ORCID,de Cózar Abel¹²³⁴^ORCID,Sierra Miguel A.³⁵^ORCID,Casarrubios Luis³⁵^ORCID,Muntaner Jaime G.³⁵,Banik Bimal K.⁶⁷,Bandyopadhyay Debasish⁷^ORCID

Affiliation:

1. Kimika Fakultatea, Kimika Organikoa I Saila, Universidad del País Vasco – Euskal Herriko Unibertsitaea, P. K. 1071, 28018 San Sebastián-Donostia, Spain

2. Donostia International Physics Centre (DIPC), P.O. Box 1072, 20018 San Sebastián-Donostia, Spain

3. Centro de Innovación en Química Avanzada (ORFEO-CINQA), Spain

4. IKERBASQUE, Basque Foundation for Science, 48009 Bilbao, Spain

5. Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Complutense, 28040 Madrid, Spain

6. Department of Mathematics and Natural Sciences, College of Sciences and Human Studies, Deanship of Research, Prince Mohammad Bin Fahd University, Al Khobar, Kingdom of Saudi Arabia

7. Department of Chemistry, The University of Texas-Pan American, 1201 West University Drive, Edinburg, Texas 78541, USA

Abstract

Experimental and computational studies reveal the importance of isomerization pathways in the Staudinger reaction between ketenes and imines. In the studied cases, the stereochemistry is determined by the pre-cycloaddition isomerization step.

Funder

Eusko Jaurlaritza

Ministerio de Ciencia e Innovación

Fundación Ramón Areces

National Institutes of Health

National Cancer Institute

Prince Mohammad Bin Fahd University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RA/D1RA06114C

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