Harnessing the electronic structure of active metals to lower the overpotential of the electrocatalytic oxygen evolution reaction

Author:

Baldinelli Lorenzo1ORCID,Rodriguez Gabriel Menendez1ORCID,D'Ambrosio Iolanda1,Grigoras Amalia Malina1ORCID,Vivani Riccardo2ORCID,Latterini Loredana1ORCID,Macchioni Alceo1ORCID,De Angelis Filippo1345ORCID,Bistoni Giovanni1ORCID

Affiliation:

1. Dipartmento di Chimica, Biologia e Biotecnologie, Università Degli Studi Di Perugia, Via Elce di sotto, 8, 06123 Perugia, Italy

2. Dipartimento di Scienze Farmaceutiche, Università Degli Studi Di Perugia, Via del Liceo, 06123 Perugia, Italy

3. Computational Laboratory for Hybrid/Organic Photovoltaics (CLHYO), Istituto CNR di Scienze e Tecnologie Chimiche “Giulio Natta” (CNR-SCITEC), 06123 Perugia, Italy

4. Department of Mechanical Engineering, College of Engineering, Prince Mohammad Bin Fahd University, Al Khobar 31952, Saudi Arabia

5. SKKU Institute of Energy Science and Technology (SIEST), Sungkyunkwan University, Suwon 440-746, Korea

Abstract

An integrated computational and experimental strategy is used to shed light on the mechanism of the OER on coordination polymers of earth abundant metals, revealing the crucial influence of spin and oxidation state changes on the overpotential.

Funder

Ministero dell'Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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