Desulfonative photoredox alkylation of N-heteroaryl sulfones – an acid-free approach for substituted heteroarene synthesis-Reference-Cited by-同舟云学术

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Desulfonative photoredox alkylation of N-heteroaryl sulfones – an acid-free approach for substituted heteroarene synthesis

Published:2019 Issue:16 Volume:10 Page:4389-4393
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wang Zheng-Jun¹²³⁴⁵^ORCID,Zheng Shuai¹²³⁴⁵^ORCID,Matsui Jennifer K.¹²³⁴⁵^ORCID,Lu Zhipeng¹²³⁴⁵^ORCID,Molander Gary A.¹²³⁴⁵^ORCID

Affiliation:

1. Roy and Diana Vagelos Laboratories

2. Department of Chemistry

3. University of Pennsylvania

4. Philadelphia

5. USA

Abstract

Photoredox-mediated alkylation of heteroaryl sulfones under redox-neutral, acid-free conditions to create drug-like molecules.

Funder

National Institute of General Medical Sciences

NIH Office of the Director

China Scholarship Council

Bristol-Myers Squibb

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC00776H

Reference37 articles.

1. Privileged scaffolds for library design and drug discovery

2. Analysis of the Structural Diversity, Substitution Patterns, and Frequency of Nitrogen Heterocycles among U.S. FDA Approved Pharmaceuticals

3. Nucleophilic character of alkyl radicals—VI

4. Homolytic alkylation of protonated heteroaromatic bases by alkyl iodides, hydrogen peroxide, and dimethyl sulfoxide

5. Minisci reactions: Versatile CH-functionalizations for medicinal chemists

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