Modulating the magnetic behavior of Fe(ii)–MOF-74 by the high electron affinity of the guest molecule-Reference-Cited by-同舟云学术

Modulating the magnetic behavior of Fe(ii)–MOF-74 by the high electron affinity of the guest molecule

Published:2015 Issue:26 Volume:17 Page:16977-16982
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Han Sungmin¹²³⁴⁵,Kim Heejin¹²³⁴⁵,Kim Jaehoon¹²³⁴⁵,Jung Yousung¹²³⁴⁵

Affiliation:

1. Graduate School of Energy

2. Environment

3. Water and Sustainability (EEWS)

4. Korea Advanced Institute of Science and Technology

5. Daejeon

Abstract

The O₂ adsorption on Fe–MOF-74, which has high electron affinity, can induce a largely enhanced FM coupling between the intrachain Fe centers in Fe–MOF-74 through the superexchange interaction compared to Bare Fe–MOF-74, and it also leads to a different intrachain magnetic behavior in comparison with the olefin adsorbed Fe–MOF-74.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP01441G

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