Reaction dynamics as the missing puzzle piece: the origin of selectivity in oxazaborolidinium ion-catalysed reactions-Reference-Cited by-同舟云学术

Reaction dynamics as the missing puzzle piece: the origin of selectivity in oxazaborolidinium ion-catalysed reactions

Published:2023 Issue:43 Volume:14 Page:12355-12365
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Lam Ching Ching¹^ORCID,Goodman Jonathan M.¹^ORCID

Affiliation:

1. Yusuf Hamied Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, UK

Abstract

The selectivity in a group of oxazaborolidinium ion-catalysed reactions between aldehyde and diazo compounds cannot be explained using transition state theory.

Funder

Engineering and Physical Sciences Research Council

Science and Technology Facilities Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC03009A

Reference50 articles.

1. Computing organic stereoselectivity – from concepts to quantitative calculations and predictions

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5. “Concerted” Transition State, Stepwise Mechanism. Dynamics Effects in C2-C6 Enyne Allene Cyclizations

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