Relativistic effects on the 125Te and 33S NMR chemical shifts of various tellurium and sulfur species, together with 77Se of selenium congeners, in the framework of a zeroth-order regular approximation: applicability to tellurium compounds-Reference-Cited by-同舟云学术

Relativistic effects on the 125Te and 33S NMR chemical shifts of various tellurium and sulfur species, together with 77Se of selenium congeners, in the framework of a zeroth-order regular approximation: applicability to tellurium compounds

Published:2014 Issue:84 Volume:4 Page:44795-44810
ISSN:2046-2069
Container-title:RSC Adv.
language:en
Short-container-title:RSC Adv.

Author:

Hayashi Satoko¹²³⁴,Matsuiwa Kohei¹²³⁴,Nakanishi Waro¹²³⁴

Affiliation:

1. Department of Material Science and Chemistry

2. Faculty of Systems Engineering

3. Wakayama University

4. Wakayama 640-8510, Japan

Abstract

The relativistic effects on σ(Te), σ(Se), and σ(S) were evaluated separately by scalar and spin–orbit terms for various species containing Te, Se, and S nuclei. The applicability of σ^t(Te)_Rlt-so to analyze δ(Te)_obsd and the trend in the nuclei are discussed.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/RA/C4RA07818G

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