Reactivity of aminophosphonic acids. Oxidative dephosphonylation of 1-aminoalkylphosphonic acids by aqueous halogens

Author:

Drabowicz Józef12345,Jordan Frank678910,Kudzin Marcin H.11123,Kudzin Zbigniew H.1314153,Stevens Christian V.1617181920,Urbaniak Paweł1314153

Affiliation:

1. Centre of Molecular and Macromolecular Studies

2. Polish Academy of Sciences

3. Poland

4. Jan Długosz University

5. Department of Chemistry and Environment Protection

6. Department of Chemistry

7. Rutgers

8. The State University

9. Newark

10. USA

11. Textile Research Institute

12. Lodz 92-103

13. Faculty of Chemistry

14. University of Lodz

15. Lodz 90-136

16. Ghent University

17. Faculty of Bioscience Engineering

18. Department of Sustainable Organic Chemistry and Technology

19. Ghent B-9000

20. Belgium

Abstract

The quantitative halogen-promoted dephosphonylation of AAPoccursviapentacoordinate phosphorus derivative3with the formation of phosphoric acid, carbonyls and nitrogen.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference51 articles.

1. Aminophosphonic and Aminophosphinic Acids: Chemistry and Biological Activity, ed. V. P. Kukhar and H. R. Hudson, J. Wiley & Sons, Ltd, Chichester, New York, Weinheim, Brisbane, Singapore, Toronto, 2000

2. Organophosphorus Complexones

3. Synthetic and structural aspects of the chemistry of saturated polyaza macrocyclic ligands bearing pendant coordinating groups attached to nitrogen

4. T. Kiss and I.Lazar, Stability constants of metal complexes in solution, in Aminophosphonic and aminophosphinic acids. Chemistry and biological activity, ed. V. P. Kukhar and H. R. Hudson, J. Wiley & Sons, Ltd., Chichester, New York, Weinheim, Brisbane, Singapore, Toronto, 2000, ch. 9, pp. 285–326

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