Investigating the role of GeO2 in enhancing the thermal stability and proton mobility of proton-conducting phosphate glasses

Author:

Omata Takahisa1ORCID,Sharma Aman1ORCID,Kinoshita Takuya2,Suzuki Issei1ORCID,Ishiyama Tomohiro3ORCID,Kohara Shinji4567ORCID,Ohara Koji7ORCID,Ono Madoka2ORCID,Fang Tong8,Ren Yang8ORCID,Fujioka Masaya2ORCID,Zhao Gaoyang8,Nishii Junji2ORCID

Affiliation:

1. Institute of Multidisciplinary Research for Advanced Materials (IMRAM), Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan

2. Research Institute for Electronic Science, Hokkaido University, Kita 21 Nishi 10, Kita-ku, Sapporo 001-0021, Japan

3. Fuel Cell Materials Group, Research Institute for Energy Conservation, National Institute of Advanced Industrial Science and Technology (AIST), AIST Central 5, Higashi 1-1-1, Tsukuba, Ibaraki 305-8565, Japan

4. Center for Materials Research by Information Integration (CMI2), Research and Services Division of Materials Data and Integrated System (MaDIS), National Institute for Materials Science (NIMS), Ibaraki 305-0047, Japan

5. Research Center for Advanced Measurement and Characterization, NIMS, Sayo-gun, Hyogo 679-5148, Japan

6. PRESTO, Japan Science and Technology Agency, Chiyoda-ku, Tokyo 102-0076, Japan

7. Diffraction and Scattering Division, Japan Synchrotron Radiation Research Institute (JASRI), Sayo-gun, Hyogo 679-5198, Japan

8. School of Materials Sciences and Technology, Xi'an University of Technology, Xi'an 710048, China

Abstract

In this study, the effect of GeO2 on the thermal stability and proton mobility (μH) of proton-conducting phosphate glasses was experimentally investigated using 22HO1/2–3NaO1/2–(12 − x)LaO3/2xGeO2–63PO5/2 glasses.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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