Highly selective Suzuki reaction catalysed by a molecular Pd–P-MOF catalyst under mild conditions: role of ligands and palladium speciation-Reference-Cited by-同舟云学术

Highly selective Suzuki reaction catalysed by a molecular Pd–P-MOF catalyst under mild conditions: role of ligands and palladium speciation

Published:2022 Issue:3 Volume:12 Page:954-961
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Cartagenova Daniele¹^ORCID,Bachmann Stephan²,Püntener Kurt²,Scalone Michelangelo²,Newton Mark A.³^ORCID,Peixoto Esteves Fabio A.¹^ORCID,Rohrbach Thomas¹,Zimmermann Patrik P.¹,van Bokhoven Jeroen A.¹³^ORCID,Ranocchiari Marco¹^ORCID

Affiliation:

1. Laboratory for Catalysis and Sustainable Chemistry, Paul Scherrer Institut, Forschungsstrasse 111, 5232 Villigen PSI, Switzerland

2. Pharmaceutical Division, Synthetic Molecules Technical Development, Department of Process Chemistry and Catalysis, F. Hoffmann-La Roche Ltd, Grenzacherstrasse 124, 4070 Basel, Switzerland

3. Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog-Weg 1-5, 8093 Zurich, Switzerland

Abstract

A phosphine-functionalized MOF was used to prepare molecularly-defined palladium catalysts, active for Suzuki coupling in mild conditions. Their selectivity was correlated with the nature of the catalytic active site via XAS and NMR.

Funder

F. Hoffmann-La Roche

Energy System Integration, Paul Scherrer Institut

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CY/D1CY01351C

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