Developing bulky P-alkene ligands: stabilization of copper complexes with 14 valence electrons-Reference-Cited by-同舟云学术

Developing bulky P-alkene ligands: stabilization of copper complexes with 14 valence electrons

Published:2023 Issue:5 Volume:47 Page:2307-2323
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Grasruck Alexander¹,Parla Giorgio¹,Heineman Frank W.¹,Langer Jens²^ORCID,Herrera Alberto¹,Frieß Sybille¹,Schmid Günter³^ORCID,Dorta Romano¹^ORCID

Affiliation:

1. Anorganische und Allgemeine Chemie, Department Chemie und Pharmazie, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 1, 91058 Erlangen, Germany

2. Anorganische und Metallorganische Chemie, Department Chemie und Pharmazie, Friedrich–Alexander–Universität Erlangen–Nürnberg, Egerlandstraße 1, 91058 Erlangen, Germany

3. Siemens Energy Global GmbH & Co. KG, New Energy Business – Technology & Products, Freyeslebenstraße 1, 91058 Erlangen, Germany

Abstract

The superbulky P-alkene ligand 21 is prepared from dibenzoazepine and stabilizes the highly unsaturated cationic Cu(i)-complex 26.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/NJ/D2NJ05222A

Reference74 articles.

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2. “Chiral-at-Metal” Hemilabile Nickel Complexes with a Latent d10-ML2Configuration: Receiving Substrates with Open Arms

3. Tri(1-cyclohepta-2,4,6-trienyl)phosphan, P(C7H7)3 und Tetra(1-cyclohepta-2,4,6-trienyl)phosphonium-tetrafluoroborat, [P(C7H7)4]BF4

4. Dibenzotropylidene phosphanes (TROPPs): synthesis and coinage metal complexes

5. Iridium-Catalyzed Synthesis of Primary Allylic Amines from Allylic Alcohols: Sulfamic Acid as Ammonia Equivalent

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1. Dibenzoazepine hydrazine is a building block for N-alkene hybrid ligands: exploratory syntheses of complexes of Cu, Fe, and Li;Dalton Transactions;2024

2. Trapping of soluble, KCl-stabilized Cu(i) hydrides with CO₂ gives crystalline formates;Chemical Communications;2023