Hydrophobicity effects in iron polypyridyl complex electrocatalysis within Nafion thin-film electrodes

Abstract

Four polypyridyl redox catalysts Fe(bp)₃²⁺, Fe(ph)₃²⁺, Fe(dm)₃²⁺, and Fe(tm)₃²⁺ (with bp, ph, dm, and tm representing 2,2′-bipyridine, 1,10-phenanthroline, 4,4′-dimethyl-2,2′-bipyridine, and 3,4,7,8-tetramethyl-1,10-phenanthroline, respectively) are investigated for the electrocatalytic oxidation of three analytes (nitrite, arsenite, and isoniazid).