Excited-state dynamics of a molecular dyad with two orthogonally-oriented fluorophores

Author:

Letrun Romain1234ORCID,Lang Bernhard1234ORCID,Yushchenko Oleksandr1234,Wilcken Roland5678ORCID,Svechkarev Denis9101112ORCID,Kolodieznyi Dmytro131415,Riedle Eberhard5678ORCID,Vauthey Eric1234ORCID

Affiliation:

1. Department of Physical Chemistry

2. University of Geneva

3. CH-1211 Geneva 4

4. Switzerland

5. Lehrstuhl für BioMolekulare Optik

6. Ludwig-Maximilians-Universität München

7. 80538 München

8. Germany

9. Department of Pharmaceutical Sciences

10. University of Nebraska Medical Center

11. Omaha

12. USA

13. V.N. Karazin Kharkiv National University

14. Kharkiv 61022

15. Ukraine

Abstract

Intramolecular charge separation and enhanced spin orbit coupling explain the weak fluorescence of a T-shaped dyad comprising two strong fluorophores.

Funder

Deutsche Forschungsgemeinschaft

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Munich-Centre for Advanced Photonics

Université de Genève

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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