Chiral oxamide–phosphine–palladium catalyzed highly asymmetric allylic amination: carbonyl assistance for high regio- and enantiocontrols-Reference-Cited by-同舟云学术

Chiral oxamide–phosphine–palladium catalyzed highly asymmetric allylic amination: carbonyl assistance for high regio- and enantiocontrols

Published:2022 Issue:15 Volume:9 Page:3976-3989
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Chen Jun-Bo¹,Peng Cheng¹,Zhou Sheng-Suo¹,Wang Yong¹^ORCID,Wang Zheng²,Wang Xing-Wang¹^ORCID

Affiliation:

1. Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China

2. State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P. R. China

Abstract

The chiral oxamide–phosphine (COAP) ligands were developed for the palladium-catalyzed asymmetric allylic amination of vinyl benzoxazinones with alkylamines, affording a series of optically active diamines in good yields with high enantioselectivity.

Funder

National Natural Science Foundation of China

Program for New Century Excellent Talents in University

Priority Academic Program Development of Jiangsu Higher Education Institutions

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QO/D2QO00458E

Reference69 articles.

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5. Renaissance of pyridine-oxazolines as chiral ligands for asymmetric catalysis

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