Enantioselective [3 + 2] cycloaddition and rearrangement of thiazolium salts to synthesize thiazole and 1,4-thiazine derivatives
Author:
Affiliation:
1. Key Laboratory of Green Chemistry & Technology
2. Ministry of Education
3. College of Chemistry
4. Sichuan University
5. Chengdu 610064
Abstract
A highly efficient catalytic asymmetric [3 + 2] cycloaddition/rearrangement cascade of thiazolium N-ylides with various electron-deficient 2-π components was achieved, providing a convenient method to access hydropyrrolo-thiazole and hydropyrrolo-thiazine derivatives.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/QO/C8QO00370J
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