Structural evolution, optical gap and thermoelectric properties of CH3NH3SnBr3 hybrid perovskite, prepared by mechanochemistry

Author:

López Carlos A.12345,Abia Carmen12345,Gainza Javier12345ORCID,Kayser Paula12345ORCID,Nemes N. N.12345ORCID,Dura O. J.675ORCID,Martínez J. L.12345ORCID,Fernández-Díaz María T.891011,Álvarez-Galván Consuelo122345,Alonso José A.12345ORCID

Affiliation:

1. Instituto de Ciencia de Materiales de Madrid

2. CSIC

3. Cantoblanco

4. 28049 Madrid

5. Spain

6. Departamento de Física Aplicada

7. Universidad de Castilla-La Mancha

8. Institut Laue Langevin

9. BP 156X

10. F-38042 Grenoble

11. France

12. Instituto de Catálisis y Petroleoquímica

Abstract

From the cubic phase at RT, three superstructures are identified down to 120 K result from the octahedral SnBr6 tilting and the stereochemical effect of Sn2+ lone pair. The Seebeck coefficient is ∼2000 μV K−1 at RT.

Funder

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Microbiology

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