The influence of π-conjugation on competitive pathways: charge transfer or electron transfer in new D–π–A and D–π–Si–π–A dyads
Author:
Affiliation:
1. Department of Advanced Materials Chemistry
2. Korea University (Sejong)
3. Sejong
4. South Korea
5. Department of Chemistry
6. Seoul Women's University
7. Seoul
8. Center for Photovoltaic Materials
Abstract
Intramolecular charge transfer results in a partial charge transfer species (Dδ+–π–Aδ−). The disconnection of π-conjugation between the donor and acceptor causes a unit-electron transfer to form D˙+–π–Si–π–A˙− species.
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP03259A
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