Exploring the effect of axial ligands, solvation, and redox on structure and inter-metal communication in Fe<sub>3</sub>-EMACs-Reference-Cited by-同舟云学术

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Exploring the effect of axial ligands, solvation, and redox on structure and inter-metal communication in Fe₃-EMACs

Published:2024 Issue:24 Volume:48 Page:10943-10948
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Obies Mohammed¹^ORCID

Affiliation:

1. College of Pharmacy, University of Babylon, 51002, Hillah, Babylon, Iraq

Abstract

The structure and bonding between Fe–Fe ions in the Fe3-EMACs complexes are not affected by the capped ligands (NCS−, CN−, and NO3−). However, the redox processes alter the structure of Fe3-EMAC from symmetrical to unsymmetrical.

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NJ/D4NJ01164C

Reference41 articles.

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2. M.Majumdar and J. K.Bera , in Macromolecules Containing Metal and Metal-Like Elements , ed. A. Abd-El Aziz , C. E. Carraher , C. U. Pittman and M. Zeldin , John Wiley & Sons, Inc ., 2009 , vol. 9, pp. 182–253

3. From Homonuclear Metal String Complexes to Heteronuclear Metal String Complexes

4. Additional Steps toward Molecular Scale Wires: Further Study of Ni510/11+ Chains Embraced by Polypyridylamide Ligands

5. G.Parkin , Metal−Metal Bonding , Structure and Bonding , Springer , Heidelberg, Germany , 2010

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