Synthesis and characterization of one-handed helical oligo(<i>o</i>-phenylene)s: control of axial chirality by planar chiral [2.2]paracyclophane-Reference-Cited by-同舟云学术

Synthesis and characterization of one-handed helical oligo(o-phenylene)s: control of axial chirality by planar chiral [2.2]paracyclophane

Published:2024 Issue:11 Volume:60 Page:1468-1471
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Yanagawa Asuka¹,Inoue Ryo¹^ORCID,Morisaki Yasuhiro¹^ORCID

Affiliation:

1. Department of Applied Chemistry for Environment, School of Biological and Environmental Sciences, Kwansei Gakuin University, 1 Gakuen Uegahara, Sanda, Hyogo 669-1330, Japan

Abstract

Helical oligo(o-phenylene)-layered molecules were synthesized from planar chiral [2.2]paracyclophane. The o-quinquephenyl-layered molecule was emissive, and circularly polarized luminescence was observed with a high anisotropy factor (|glum| value).

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D3CC05000A

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