Substrate geometry controls the cyclization cascade in multiproduct terpene synthases from Zea mays-Reference-Cited by-同舟云学术

Substrate geometry controls the cyclization cascade in multiproduct terpene synthases from Zea mays

Published:2015 Issue:21 Volume:13 Page:6021-6030
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Vattekkatte Abith¹²³⁴,Gatto Nathalie¹²³⁴,Köllner Tobias G.⁵²³⁴,Degenhardt Jörg⁶⁷⁸⁴,Gershenzon Jonathan⁵²³⁴,Boland Wilhelm¹²³⁴

Affiliation:

1. Department of Bioorganic Chemistry

2. Max Planck Institute for Chemical Ecology

3. D-07745 Jena

4. Germany

5. Department of Biochemistry

6. Institute for Pharmacy

7. University of Halle

8. D-06120 Halle

Abstract

Multiproduct terpene synthases on incubation with (2Z) substrates showed enhanced enzymatic turnover with distinct preference for cyclic products than corresponding (2E) substrates.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C5OB00711A

Reference49 articles.

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4. ABSCISIC ACID BIOSYNTHESIS AND CATABOLISM

5. The formation and function of plant volatiles: perfumes for pollinator attraction and defense

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