Impact of the coordination of multiple Lewis acid functions on the electronic structure and vn configuration of a metal center-Reference-Cited by-同舟云学术

Impact of the coordination of multiple Lewis acid functions on the electronic structure and vn configuration of a metal center

Published:2022 Issue:2 Volume:51 Page:411-427
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Parkin Gerard¹^ORCID

Affiliation:

1. Department of Chemistry, Columbia University, New York, New York 10027, USA

Abstract

The number of electrons that a metal center provides to the bonding orbitals for coordination of multiple π-acceptor ligands is not a direct function of the number of ligands, and consideration must be given to the availability of metal orbitals.

Funder

National Science Foundation

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT02921E

Reference144 articles.

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5. Complementary spherical electron density model and its implications for the 18 electron rule

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