Highly efficient synthesis of unsymmetrical 1,3-diynes from organoalane reagents and alkynyl bromides mediated by a nickel catalyst-Reference-Cited by-同舟云学术

Highly efficient synthesis of unsymmetrical 1,3-diynes from organoalane reagents and alkynyl bromides mediated by a nickel catalyst

Published:2017 Issue:44 Volume:7 Page:27243-27247
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Mo Song¹²³⁴,Shao Xue-Bei¹²³⁴,Zhang Gang¹²³⁴,Li Qing-Han¹²³⁴^ORCID

Affiliation:

1. College of Chemistry and Environmental Protection Engineering

2. Southwest University for Nationalities

3. Chengdu 610041

4. P. R. China

Abstract

Highly efficient and simple cross-coupling reactions of alkynylbromides with organoalane reagents for the synthesis of unsymmetrical 1,3-diynes derivatives using Ni(OAc)₂ (2–5 mol%)/(o-furyl)₃P (4–10 mol%) as a catalyst are reported.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/RA/C7RA02758C

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