Unveiling the mechanism of the photocatalytic reduction of CO<sub>2</sub> to formate promoted by porphyrinic Zr-based metal–organic frameworks-Reference-Cited by-同舟云学术

Unveiling the mechanism of the photocatalytic reduction of CO₂ to formate promoted by porphyrinic Zr-based metal–organic frameworks

Published:2022 Issue:35 Volume:10 Page:18103-18115
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Benseghir Youven¹²,Solé-Daura Albert¹^ORCID,Cairnie Daniel R.³^ORCID,Robinson Amanda L.¹,Duguet Mathis¹²,Mialane Pierre²,Gairola Priyanka²⁴,Gomez-Mingot Maria¹^ORCID,Fontecave Marc¹^ORCID,Iovan Diana³^ORCID,Bonnett Brittany³,Morris Amanda J.³^ORCID,Dolbecq Anne²^ORCID,Mellot-Draznieks Caroline¹^ORCID

Affiliation:

1. Laboratoire de Chimie des Processus Biologiques, UMR CNRS 8229, Collège de France, Sorbonne Université, PSL Research University, 11 Place Marcelin Berthelot, 75231 Paris Cedex 05, France

2. Université Paris-Saclay, UVSQ, CNRS UMR 8180, Institut Lavoisier de Versailles, 78000 Versailles, France

3. Department of Chemistry, Virginia Tech, Blacksburg, Virginia, 24060, USA

4. Institut de Chimie Moléculaire et des Matériaux d’Orsay, CNRS, Université Paris-Sud, Université Paris-Saclay, F-91405 Orsay, France

Abstract

A complete picture of the reaction mechanism driving the photocatalytic reduction of CO2 into formate promoted by the Zr-based porphyrinic MOF-545 in CH3CN/TEOA solutions is provided for the first time by combining experimental and computational approaches.

Funder

U.S. Department of Energy

Agence Nationale de la Recherche

Centre National de la Recherche Scientifique

Université de Versailles Saint-Quentin-en-Yvelines

Ministère de l'Enseignement supérieur, de la Recherche et de l'Innovation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/TA/D2TA04164B