A mesoporous metal–organic framework based on a shape-persistent macrocycle

Author:

Chen Teng-Hao1234,Popov Ilya1234,Chuang Yu-Chun567,Chen Yu-Sheng89104,Miljanić Ognjen Š.1234

Affiliation:

1. Department of Chemistry

2. University of Houston

3. Houston TX 77204-5003

4. USA

5. National Synchrotron Radiation Research Center

6. Hsinchu

7. Taiwan

8. Center for Advanced Radiation Source (ChemMatCARS)

9. The University of Chicago c/o APS/ANL

10. Argonne

Abstract

A mesoporous metal–organic framework (Zn-MCMOF) with 86% void volume was synthesized from Zn atoms and a shape-persistent macrocyclic ligand based on a phenylene ethynylene scaffold. Upon activation, pores of theZn-MCMOFcollapse, but are then regenerated through resolvation of crystals.

Funder

Research Corporation for Science Advancement

Division of Chemistry

Basic Energy Sciences

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference37 articles.

1. Metal-Organic Frameworks: Applications from Catalysis to Gas Storage, ed. D. Farrusseng, Wiley-VCH, Weinheim, 2011

2. Metal-Organic Frameworks: Design and Applications, ed. L. R. MacGillivray, Wiley, Hoboken, 2010

3. Special issue of Chem. Rev., 2012, 112, 673–1268

4. Special issue of Chem. Soc. Rev., 2014, 43, 5415–6172

5. Metal–Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit?

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