Vibronic optical spectroscopy of cryogenic flavin ions: the O2+ and N1 tautomers of protonated lumiflavin-Reference-Cited by-同舟云学术

Vibronic optical spectroscopy of cryogenic flavin ions: the O2+ and N1 tautomers of protonated lumiflavin

Published:2020 Issue:33 Volume:22 Page:18328-18339
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Müller David¹²³⁴,Dopfer Otto¹²³⁴^ORCID

Affiliation:

1. Institut für Optik und Atomare Physik

2. Technische Universität Berlin

3. D-10623 Berlin

4. Germany

Abstract

The electronic structure of cryogenic protonated lumiflavin ions probed by photodissociation spectroscopy and density functional theory calculations reveals the presence of the two most stable tautomers protonated at the O2+ and N1 positions.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP03650A

Reference39 articles.

1. The Chemical and Biological Versatility of Riboflavin

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4. Old Chromophores, New Photoactivation Paradigms, Trendy Applications: Flavins in Blue Light-Sensing Photoreceptors†

5. Structure and Function of DNA Photolyase and Cryptochrome Blue-Light Photoreceptors

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