Failure modes of protection layers produced by atomic layer deposition of amorphous TiO2 on GaAs anodes
Author:
Affiliation:
1. Division of Engineering and Applied Sciences
2. California Institute of Technology
3. Pasadena
4. USA
5. Division of Chemistry and Chemical Engineering
6. Beckman Institute and Molecular Materials Research Center
Abstract
Extrinsic pinhole defects formed during deposition and testing control the short-term protective performance of the a-TiO2 film for GaAs anodes evolving O2 from water
Funder
Office of Science
Publisher
Royal Society of Chemistry (RSC)
Subject
Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/EE/D0EE02032J
Reference22 articles.
1. Amorphous TiO 2 coatings stabilize Si, GaAs, and GaP photoanodes for efficient water oxidation
2. Solar-Driven Reduction of 1 atm of CO2 to Formate at 10% Energy-Conversion Efficiency by Use of a TiO2-Protected III–V Tandem Photoanode in Conjunction with a Bipolar Membrane and a Pd/C Cathode
3. Stabilization of Si microwire arrays for solar-driven H2O oxidation to O2(g) in 1.0 M KOH(aq) using conformal coatings of amorphous TiO2
4. Stabilization of n-cadmium telluride photoanodes for water oxidation to O2(g) in aqueous alkaline electrolytes using amorphous TiO2 films formed by atomic-layer deposition
5. A monolithically integrated, intrinsically safe, 10% efficient, solar-driven water-splitting system based on active, stable earth-abundant electrocatalysts in conjunction with tandem III–V light absorbers protected by amorphous TiO2 films
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