Cationic indium complexes for the copolymerization of functionalized epoxides with cyclic ethers and lactide-Reference-Cited by-同舟云学术

Cationic indium complexes for the copolymerization of functionalized epoxides with cyclic ethers and lactide

Published:2019 Issue:23 Volume:55 Page:3347-3350
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Diaz Carlos¹²³,Ebrahimi Tannaz¹²³,Mehrkhodavandi Parisa¹²³^ORCID

Affiliation:

1. University of British Columbia, Department of Chemistry

2. Vancouver

3. Canada

Abstract

Cationic indium salen complexes are active catalysts for the ring opening polymerization of epoxides and other less strained cyclic ethers. Moreover, they are competent catalysts in the copolymerization of rac-lactide and epoxides to high molecular weight copolymers. Preliminary kinetic investigations with different cationic complexes revealed subtle effects of their solvent donors in the initiation rates of polymerization of epoxides.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C8CC08858F

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