Synthesis of the first chiral polynuclear copper(i) complex based on (R)-1-(1-phenyl)ethyl-3-(O,O-diethylthiophosphoryl)thiourea and its characterization in the solid state and solution-Reference-Cited by-同舟云学术

Synthesis of the first chiral polynuclear copper(i) complex based on (R)-1-(1-phenyl)ethyl-3-(O,O-diethylthiophosphoryl)thiourea and its characterization in the solid state and solution

Published:2020 Issue:8 Volume:44 Page:3224-3231
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Metlushka Kirill E.¹²³⁴⁵^ORCID,Sadkova Dilyara N.¹²³⁴⁵,Nikitina Kristina A.¹²³⁴⁵,Pashagin Alexander V.¹²³⁴⁵,Khrizanforov Mikhail N.¹²³⁴⁵^ORCID,Budnikova Yulia H.¹²³⁴⁵^ORCID,Morozov Vladimir I.¹²³⁴⁵,Islamov Daut R.⁶⁷⁵,Latypov Shamil K.¹²³⁴⁵^ORCID,Kataeva Olga N.¹²³⁴⁵^ORCID,Alfonsov Vladimir A.¹²³⁴⁵

Affiliation:

1. Arbuzov Institute of Organic and Physical Chemistry

2. FRC Kazan Scientific Center

3. Russian Academy of Sciences

4. Kazan 420088

5. Russia

6. A.M. Butlerov Chemistry Institute of the Kazan Federal University

7. Kazan 420008

Abstract

The reaction of chiral N-thiophosphorylated thiourea with Cu(ii) acetate is accompanied by copper reduction and leads to the formation of a polynuclear complex with the core composed of six Cu(i) ions alternating with sulfur atoms.

Funder

Kazan Federal University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/NJ/C9NJ05683A

Reference43 articles.

1. Review—Organic-Inorganic Hybrid Functional Materials: An Integrated Platform for Applied Technologies

2. Photoluminescence Properties of Multinuclear Copper(I) Compounds

3. Structural and spectroscopic evidence for weak metal–metal interactions and metal–substrate exciplex formations in d10 metal complexes

4. Bright Coppertunities: Multinuclear CuIComplexes with N-P Ligands and Their Applications

5. Cu-Catalyzed Azide−Alkyne Cycloaddition

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