Physical aging of hydroxypropyl methylcellulose acetate succinate via enthalpy recovery

Author:

Seo Yejoon1ORCID,Zuo Biao2,Cangialosi Daniele34ORCID,Priestley Rodney D.15ORCID

Affiliation:

1. Department of Chemical and Biological Engineering, Princeton University, Princeton, New Jersey 08540, USA

2. Department of Chemistry, Zhejiang Sci-Tech University, Hangzhou, 310018, China

3. Donostia International Physics Center (DIPC), Paseo Manuel de Lardizábal 4, 20018, San Sebastián, Spain

4. Centro de Fisica de Materiales (CSIC-UPV/EHU), Paseo Manuel de Lardizábal 5, 20018, San Sebastián, Spain

5. Princeton Institute for the Science and Technology of Materials, Princeton University, 41 Olden St, A215 Chemical and Biological Engineering, Princeton, New Jersey 08540, USA

Abstract

There are two regimes of physical aging behavior for HPMCAS: near-Tg and well below Tg. The latter regime exhibits significant thermodynamic evolution, despite the assumed kinetic stability.

Funder

National Science Foundation

Ministerio de Ciencia, Innovación y Universidades

Eusko Jaurlaritza

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Chemistry

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