Carbohydrate-based N-heterocyclic carbenes for enantioselective catalysis-Reference-Cited by-同舟云学术

Carbohydrate-based N-heterocyclic carbenes for enantioselective catalysis

Published:2014 Issue:45 Volume:12 Page:9180-9183
ISSN:1477-0520
Container-title:Org. Biomol. Chem.
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Henderson Alexander S.¹²³,Bower John F.¹²³,Galan M. Carmen¹²³

Affiliation:

1. School of Chemistry

2. University of Bristol

3. Bristol BS8 1TS, UK

Abstract

Versatile syntheses of C2-linked and C₂-symmetric carbohydrate-based NHC·HCls from functionalised amino-carbohydrate derivatives are reported. The corresponding Rh complexes were evaluated in asymmetric hydrosilylation of ketones.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/OB/C4OB02056A

Reference40 articles.

1. N-Heterocyclic Carbenes

2. N-Heterocyclic Carbenes in Late Transition Metal Catalysis

3. Synthesis and Application of Water-Soluble NHC Transition-Metal Complexes

4. Synthetic Routes to N-Heterocyclic Carbene Precursors

5. Chiral N-heterocyclic carbenes as stereodirecting ligands in asymmetric catalysis

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