High turnover in electro-oxidation of alcohols and ethers with a glassy carbon-supported phenanthroimidazole mediator-Reference-Cited by-同舟云学术

High turnover in electro-oxidation of alcohols and ethers with a glassy carbon-supported phenanthroimidazole mediator

Published:2017 Issue:9 Volume:8 Page:6493-6498
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Johnson Bruce M.¹²³⁴,Francke Robert⁵⁶⁷⁸,Little R. Daniel⁹²¹⁰⁴,Berben Louise A.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of California

3. Davis

4. USA

5. Institut für Chemie

6. Abteilung Technische Chemie

7. Universität Rostock

8. Germany

9. Department of Chemistry and Biochemistry

10. Santa Barbara

Abstract

Glassy carbon electrodes covalently modified with a phenanthroimidazole mediator promote electrochemical alcohol and ether oxidation: three orders of magnitude increase in TON, to ∼15 000 in each case, was observed compared with homogeneous mediated reactions.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC02482G

Reference35 articles.

1. Organic electrosynthesis: a promising green methodology in organic chemistry

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4. Industrial Oxidations with Organocatalyst TEMPO and Its Derivatives

5. Novel Triarylimidazole Redox Catalysts: Synthesis, Electrochemical Properties, and Applicability to Electrooxidative C–H Activation

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