Aggregation of catalytically active Ru nanoparticles to inactive bulk, monitored in situ during an allylic isomerization reaction. Influence of solvent, surfactant and stirring
Author:
Affiliation:
1. Institute of Chemistry
2. The Hebrew University of Jerusalem
3. Jerusalem
4. Israel
Abstract
To explain the decay of the activity of Ru-NPs catalysts, that formed in situ during allylic isomerization, we add a new step to a classic mechanism of transition-metal NPs self-assembly: the aggregation of two catalytically active NPs (C) to inactive bulk-metal (D).
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/RA/C7RA11133A
Reference48 articles.
1. Nanoparticles as Recyclable Catalysts: The Frontier between Homogeneous and Heterogeneous Catalysis
2. On the Nature of the Active Species in Palladium Catalyzed Mizoroki–Heck and Suzuki–Miyaura Couplings – Homogeneous or Heterogeneous Catalysis, A Critical Review
3. Corrigendum to “Asymmetric catalytic reduction of carbonyl compounds using C2 symmetric diamines as chiral ligands”
4. Ligand-stabilized metal clusters and colloids: properties and applications
Cited by 7 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Oxo-centered trinuclear ruthenium acetates: Structure and applications;Coordination Chemistry Reviews;2023-11
2. Synthesis of Palladium Nanoparticles Supported over Fused Graphene-like Material for Hydrogen Evolution Reaction;Catalysts;2023-07-17
3. Phytogenically bioengineered metal nanoarchitecture for degradation of refractory dye water pollutants: A pragmatic minireview;Applied Organometallic Chemistry;2022-11-17
4. Trimeric Ruthenium Cluster-Derived Ru Nanoparticles Dispersed in MIL-101(Cr) for Catalytic Transfer Hydrogenation;Catalysts;2022-09-06
5. Effect of Support Nature on Ruthenium-Catalyzed Allylic Oxidation of Cycloalkenes;Catalysis Letters;2022-01-06
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3