A metal–organic framework modulated to site-isolate Cl˙ pendants <i>via</i> radical inter-conversion for degrading hard-to-ionize aqueous organic wastes-Reference-Cited by-同舟云学术

A metal–organic framework modulated to site-isolate Cl˙ pendants via radical inter-conversion for degrading hard-to-ionize aqueous organic wastes

Published:2023 Issue:17 Volume:11 Page:9436-9454
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Kim Minsung¹²^ORCID,Al Mamunur Rashid Md¹^ORCID,Choe Yun Jeong¹,Kim Sang Hoon¹^ORCID,Lee Jung-Hyun²^ORCID,Jeong Keunhong³,Kim Jongsik⁴^ORCID

Affiliation:

1. Extreme Materials Research Center, Korea Institute of Science and Technology, Seoul, 02792, South Korea

2. Department of Chemical and Biological Engineering, Korea University, Seoul, 02841, South Korea

3. Department of Physics and Chemistry, Korea Military Academy, Seoul, 01805, South Korea

4. Department of Chemical Engineering, Kyung Hee University, Yongin, 17104, South Korea

Abstract

UiO-66 is modulated to bear Zr4+/–OH to form ˙OH via H2O2 homolysis and Cl− pendants to form Cl˙ analogues (Cl˙SUP) via ˙OH-mediated radicalization. Cl˙SUP enhances the activity/selectivity/reusability over ˙OH/SO4˙−SUP/NO3˙SUP in degrading aromatics.

Funder

Kyung Hee University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/TA/D2TA09999C

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