Iron piano-stool complexes containing NHC ligands outfitted with pendent arms: synthesis, characterization, and screening for catalytic transfer hydrogenation
Author:
Affiliation:
1. Center for Renewable Carbon
2. University of Tennessee
3. Knoxville
4. USA
5. USDA-Forest Service
6. Southern Research Station
7. Auburn
8. X-ray Crystallographic Facility
9. Department of Chemistry
10. University of Rochester
11. Rochester
Abstract
The reaction of hydroxyl-appended NHC ligands with FpI affords a pair of iron-containing organometallic species with interesting electronic and structural properties.
Funder
National Institute of Food and Agriculture
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA20764B
Reference43 articles.
1. R. M. Bullock , in Catalysis without Precious Metals, Wiley-VCH Verlag GmbH & Co. KGaA, 2010, pp. I–XVIII
2. Iron Catalysis in Organic Synthesis
3. N. N. Greenwood and A.Earnshaw, in Chemistry of the Elements, Butterworth-Heinemann, Oxford, 2nd edn, 1997, pp. 1070–1112
4. Steric and Electronic Properties of N-Heterocyclic Carbenes (NHC): A Detailed Study on Their Interaction with Ni(CO)4
5. F. Glorius , in N-Heterocyclic Carbenes in Transition Metal Catalysis, Springer, Berlin, Heidelberg, 2007, vol. 21, ch. 1, pp. 1–20
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