Molecular titanium nitrides: nucleophiles unleashed-Reference-Cited by-同舟云学术

Molecular titanium nitrides: nucleophiles unleashed

Published:2017 Issue:2 Volume:8 Page:1209-1224
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Grant Lauren N.¹²³⁴,Pinter Balazs⁵⁶⁷⁸,Kurogi Takashi¹²³⁴^ORCID,Carroll Maria E.¹²³⁴,Wu Gang¹⁹¹⁰¹¹,Manor Brian C.¹²³⁴,Carroll Patrick J.¹²³⁴,Mindiola Daniel J.¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of Pennsylvania

3. Philadelphia

4. USA

5. Eenheid Algemene Chemie (ALGC)

6. Vrije Universiteit Brussel (VUB)

7. Brussels

8. Belgium

9. Queen's University

10. Kingston

11. Canada K7L 3N6

Abstract

Reactivity studies of a rare example of a molecular titanium nitride are presented. A combination of theory and NMR spectroscopy provide a description of the bonding in the these nitrides, the role of the counter cation, K⁺, as well as the origin of their highly downfield ¹⁵N NMR spectroscopic shifts.

Funder

Japan Society for the Promotion of Science

University of Pennsylvania

U.S. Department of Energy

Fonds Wetenschappelijk Onderzoek

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C6SC03422E

Reference118 articles.