The first computational study for the oxidative aromatization of pyrazolines and 1,4-dihydropyridines using 1,2,4-triazolinediones: an anomeric-based oxidation

Author:

Kiafar Mahya12345,Zolfigol Mohammad Ali12345,Yarie Meysam12345,Taherpour Avat(Arman)16758

Affiliation:

1. Department of Organic Chemistry

2. Faculty of Chemistry

3. Bu-Ali Sina University

4. Hamedan

5. Iran

6. Razi University

7. Kermanshah

8. Medical Biology Research Center

Abstract

The oxidative aromatization of 1,3,5-trisubstituted pyrazolines and 1,4-dihydropyridines using 1,2,4-triazolinediones as oxidizing agents was studied. It is confirmed that the “anomeric-based oxidation” passes through a concerted oxidation via hydrogen abstraction–addition.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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