A new donor for charge-transfer systems: synthesis and properties of 2,4,7,9-tetramethyl-1,6-dithiapyrene (TMDTP) and structure of (TMDTP)3(PF6)2·2THF and TMDTP

A new donor for charge-transfer systems: synthesis and properties of 2,4,7,9-tetramethyl-1,6-dithiapyrene (TMDTP) and structure of (TMDTP)3(PF6)2·2THF and TMDTP–TCNQ

Published:2021 Issue:24 Volume:11 Page:14607-14614
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Bendix Jesper¹²³⁴,Bechgaard Klaus¹²³⁴,Christensen Jørn Bolstad¹²⁵⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Copenhagen

3. DK-2100 Copenhagen

4. Denmark

5. DK-1871 Frederiksberg

Abstract

The heterocyclic donor molecule 2,4,7,9-tetramethyl-1,6-dithiapyrene (TMDTP) has been synthesized in five steps. The charge-transfer complex, TMDTP–TCNQ, has been prepared and the salt, (TMDTP)₃(PF6)₂·2THF, obtained by electrocrystallization.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/RA/D1RA00587A

Reference46 articles.

1. Organic semiconductors, conductors and superconductors

2. Dioxapyrene-Based Organic Semiconductors for Organic Field Effect Transistors

3. Low-temperature properties of thermoelectric generators using molecular conductors

4. How Chemistry and Physics Meet in the Solid State

5. Superconductivity in a synthetic organic conductor (TMTSF)2PF 6

Cited by 3 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Synthesis and Properties of Thieno[2′,3′,4′:4,5]naphtho[1,8-cd]pyridines;The Journal of Organic Chemistry;2023-06-06

2. Charge Transfer and Level Lifetime in Molecular Photon-Absorption upon the Quantum Impedance Lorentz Oscillator;ACS Omega;2023-05-22

3. Boundary research between organic conductors and transistors: new trends for functional molecular crystals;CrystEngComm;2023