Manganese oxide as an alternative to vanadium-based catalysts for effective conversion of glucose to formic acid in water-Reference-Cited by-同舟云学术

Manganese oxide as an alternative to vanadium-based catalysts for effective conversion of glucose to formic acid in water

Published:2022 Issue:1 Volume:24 Page:315-324
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Li Jialu¹^ORCID,Smith Richard Lee²^ORCID,Xu Siyu¹,Li De¹,Yang Jirui¹,Zhang Keqiang¹^ORCID,Shen Feng¹^ORCID

Affiliation:

1. Agro-Environmental Protection Institute, Ministry of Agriculture and Rural Affairs, No. 31 Fukang Road, Nankai District, Tianjin 300191, China

2. Graduate School of Environmental Studies, Research Center of Supercritical Fluid Technology, Tohoku University, Aramaki Aza Aoba 6-6-11, Aoba, Sendai 980-8579, Japan

Abstract

MnOx was used as a vanadium-free catalyst for conversion of glucose to formic acid in water with 81% yield in which α-scission (C1–C2 bond cleavage) with arabinose being an intermediate was found to be the major conversion pathway.

Funder

National Natural Science Foundation of China

Agro-Environmental Protection Institute, Ministry of Agriculture and Rural Affairs

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/GC/D1GC03637H

Reference45 articles.

1. Room temperature, near-quantitative conversion of glucose into formic acid

2. Quantitative chemocatalytic production of lactic acid from glucose under anaerobic conditions at room temperature