Mechanisms and rates of proton transfer to coordinated carboxydithioates: studies on [Ni(S2CR){PhP(CH2CH2PPh2)2}]+ (R = Me, Et, Bun or Ph)-Reference-Cited by-同舟云学术

Mechanisms and rates of proton transfer to coordinated carboxydithioates: studies on [Ni(S2CR){PhP(CH2CH2PPh2)2}]+ (R = Me, Et, Bun or Ph)

Published:2015 Issue:7 Volume:44 Page:3307-3317
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Alwaaly Ahmed¹²³⁴⁵,Clegg William¹²³⁴,Henderson Richard A.¹²³⁴,Probert Michael R.¹²³⁴,Waddell Paul G.¹²³⁴

Affiliation:

1. School of Chemistry

2. Newcastle University

3. Newcastle upon Tyne

4. UK

5. Department of Chemistry

Abstract

Kinetics of protonation of [Ni(S₂CR)(PhP{CH₂CH₂PPh₂}₂)]⁺ (R = Me, Et, Buⁿ or Ph) with HCl reveals hydrogen-bonded precursor and subsequent chelate opening.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03543G

Reference29 articles.

1. Protonation of Unsaturated Hydrocarbon Ligands: Regioselectivity, Stereoselectivity, and Product Specificity

2. Proton Transfer, Acid-Base Catalysis, and Enzymatic Hydrolysis. Part I: ELEMENTARY PROCESSES

3. Rates of Mercapto Proton Exchange for 2-Mercaptoethanol in Aqueous Solution1a,b

4. Kinetics of Proton Transfer from Benzoylnitromethane and 1,2-Diphenyl-2-nitroethanone to Various Bases. Resonance, Inductive, Solvation, Steric, and Transition State Hydrogen-Bonding Effects on Intrinsic Rate Constants

Cited by 3 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Reperfusion-induced injury and the effects of the dithioacetate type hydrogen sulfide donor ibuprofen derivative, BM-88, in isolated rat hearts;European Journal of Pharmaceutical Sciences;2023-06

2. Synthesis, protonation and x-ray crystal structures of [Ni(SC6H3Me2-2,6){triphos}]BPh4 and [Ni(SC6H4R-2){triphos}]BPh4 {R = Me, MeO Or Cl; triphos = PhP(Ph2PCH2CH2)2}: Unusual structure when R = Cl;THE 7TH INTERNATIONAL CONFERENCE ON APPLIED SCIENCE AND TECHNOLOGY (ICAST 2019);2019

3. Slow proton transfer to coordinated carboxylates: studies on [Ni(O2CR){PhP(CH2CH2PPh2)2}]+ (R = Et or Ph);Journal of Coordination Chemistry;2015-06-17