Substantial thermal conductivity reduction in mischmetal skutterudites MmxCo4Sb12 prepared under high-pressure conditions, due to uneven distribution of the rare-earth elements

Author:

Gainza J.12345ORCID,Serrano-Sánchez F.1234ORCID,Prado-Gonjal J.12346ORCID,Nemes N. M.5784ORCID,Biskup N.57849,Dura O. J.1011124ORCID,Martínez J. L.1234ORCID,Fauth F.1314154ORCID,Alonso J. A.1234ORCID

Affiliation:

1. Instituto de Ciencia de Materiales de Madrid (ICMM)

2. Consejo Superior de Investigaciones Científicas (CSIC)

3. Madrid

4. Spain

5. Departamento de Física de Materiales

6. Departamento de Química Inorgánica

7. Universidad Complutense de Madrid

8. E-28040 Madrid

9. Instituto Pluridisciplinar

10. Departamento de Física Aplicada

11. Universidad de Castilla-La Mancha

12. Ciudad Real

13. CELLS–ALBA synchrotron

14. Cerdanyola del Valles

15. Barcelona

Abstract

Low-cost n-type Mischmetal-filled CoSb3 skutterudites with elemental filling-fraction separation, prepared at high pressure, exhibit markedly low lattice thermal conductivity.

Funder

Ministerio de Ciencia e Innovación

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Reference26 articles.

1. Complex thermoelectric materials

2. Advances in thermoelectric materials research: Looking back and moving forward

3. Thermoelectrics, an environmentally-friendly source of electrical power

4. Skutterudites as thermoelectric materials: revisited

5. DIRECTIVE 2002/95/EC OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 27 January 2003 on the restriction of the use of certain hazardous substances in electrical and electronic equipment

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