Ring-chain equilibria of dynamic macrocycles with a bis(hindered amino)disulfide linker

Author:

Takashima Rikito1,Aoki Daisuke2ORCID,Kuwata Shigeki3ORCID,Otsuka Hideyuki1ORCID

Affiliation:

1. Department of Chemical Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8550, Japan

2. Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba-shi, Chiba 263-8522, Japan

3. Department of Applied Chemistry, College of Life Sciences, Ritsumeikan University, 1-1-1 Noji-higashi, Kusatsu, Shiga 525-8577, Japan

Abstract

The effect of chain length on ring-chain equilibria was investigated to both reveal their dynamic equilibrium reactions and expand the availability of bis(2,2,6,6-tetramethylpiperidin-1-yl)disulfide (BiTEMPS)-based macrocyclic monomers.

Funder

JST-Mirai Program

Precursory Research for Embryonic Science and Technology

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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