Palladium(ii) complexes with chiral organoantimony(iii) ligands. Solution behaviour and solid state structures-Reference-Cited by-同舟云学术

Palladium(ii) complexes with chiral organoantimony(iii) ligands. Solution behaviour and solid state structures

Published:2014 Issue:51 Volume:4 Page:26569-26576
ISSN:2046-2069
Container-title:RSC Adv.
language:en
Short-container-title:RSC Adv.

Author:

Copolovici Dana¹²³⁴,Isaia Francesco⁵⁶⁷,Breunig Hans J.⁸⁹¹⁰,Raţ Ciprian I.¹²³⁴,Silvestru Cristian¹²³⁴

Affiliation:

1. Departamentul de Chimie, Centrul de Chimie Supramoleculară Organică şi Organometalică (CCSOOM)

2. Facultatea de Chimie şi Inginerie Chimică

3. Universitatea Babeş-Bolyai

4. Cluj-Napoca, Romania

5. Dipartimento di Scienze Chimiche e Geologiche

6. Università degli Studi di Cagliari

7. 09042 Monserrato (CA), Italy

8. Institut für Anorganische und Physikalische Chemie

9. Universität Bremen

10. 28334 Bremen, Germany

Abstract

The stibines R(Ph)SbCl (1) and R(Mes)₂Sb (2) (R = 2-Me₂NCH₂C₆H₄) were used to obtain [Me₂NHCH₂C₆H₅]⁺[PdCl₃{SbCl(Ph)R}]^¬ (3) and [PdCl₂{Sb(Mes)2R-N,Sb}] (4). While in 3 the intramolecular N→Sb interaction is preserved, in compound 4 the stibine 2 acts as a (N,Sb)-chelating ligand.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/RA/C4RA03482A

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