Hydroboration of an alkene by amine–boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2011/DT/C1DT10819K
Reference28 articles.
1. Transition Metal-Catalyzed Formation of Boron−Nitrogen Bonds: Catalytic Dehydrocoupling of Amine-Borane Adducts to Form Aminoboranes and Borazines
2. Homogeneous Catalytic Dehydrogenation/Dehydrocoupling of Amine-Borane Adducts by the Rh(I) Wilkinson’s Complex Analogue RhCl(PHCy2)3 (Cy = cyclohexyl)
3. Amine− and Phosphine−Borane Adducts: New Interest in Old Molecules
4. Amine− and Dimeric Amino−Borane Complexes of the {Rh(PiPr3)2}+ Fragment and Their Relevance to the Transition-Metal-Mediated Dehydrocoupling of Amine−Boranes
5. Monomeric and Oligomeric Amine−Borane σ-Complexes of Rhodium. Intermediates in the Catalytic Dehydrogenation of Amine−Boranes
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2. Investigation of the rhodium-catalyzed hydroboration of NHC-boranes: the role of alkene coordination and the origin of enantioselectivity;Dalton Transactions;2019
3. Experimental Evidence Supporting Related Mechanisms for Ru(II)-Catalyzed Dehydrocoupling and Hydrolysis of Amine-Boranes;ACS Catalysis;2017-11-09
4. Progresses on the Application of Stable Borane Adducts in the Synthesis of Organoborons;Chinese Journal of Organic Chemistry;2017
5. Olefin Hydroborations with Diamidocarbene–BH3 Adducts at Room Temperature;Catalysts;2016-09-12
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