Observation of inserted oxocarbonyl species in the tantalum cation-mediated activation of carbon dioxide dictated by two-state reactivity-Reference-Cited by-同舟云学术

Observation of inserted oxocarbonyl species in the tantalum cation-mediated activation of carbon dioxide dictated by two-state reactivity

Published:2024 Issue:1 Volume:53 Page:171-179
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Han Jia¹,Liu Pengcheng²³,Qiu Binglin¹,Wang Guanjun⁴^ORCID,Liu Shilin¹^ORCID,Zhou Xiaoguo¹^ORCID

Affiliation:

1. Hefei National Laboratory for Physical Sciences at the Microscale, Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, China

2. Anhui Institute of Optics and Fine Mechanics, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, China

3. Science Island Branch, Graduate School, University of Science and Technology of China, Hefei 230026, China

4. Department of Chemistry, Fudan University, Shanghai 200433, China

Abstract

The production of inserted oxocarbonyl species in the carbon dioxide activation by tantalum cations was identified using infrared photodissociation spectroscopy, where the oxygen atom transfer reactions are driven by two-state reactivity.

Funder

Fundamental Research Funds for the Central Universities

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D3DT03593J

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