NMR effective radius of hydrogen in XIV group hydrides evaluated by NMR spectroscopy-Reference-Cited by-同舟云学术

NMR effective radius of hydrogen in XIV group hydrides evaluated by NMR spectroscopy

Published:2017 Issue:41 Volume:46 Page:14094-14097
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Benedetti M.¹²³⁴^ORCID,De Castro F.¹²³⁴^ORCID,Ciccarese A.¹²³⁴^ORCID,Fanizzi F. P.¹²³⁴^ORCID

Affiliation:

1. Dipartimento di Scienze e Tecnologie Biologiche ed Ambientali

2. Università del Salento

3. I-73100 Lecce

4. Italy

Abstract

In the [ABr_nI_m] (A = C, Si, Ge, Sn; n + m = 4) compounds, with the heavier halido ligands bonded to the central IV group elements, the ¹³C, ²⁹Si, ⁷³Ge and ¹¹⁹Sn NMR chemical shifts were found to be linearly related to the bonded halides ionic radii overall sum, ∑(r_h). The ²⁰⁷Pb NMR chemical shift of the unstable [PbH₄] hydride could be calculated.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT03348F

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